REVERSIBILITY AND INHIBITION OF ASPHALTENE PRECIPITATION IN BRAZILIAN CRUDE OILS

A fundamental understanding of the aggregation and precipitation of asphaltenes in petroleum crudes is important for the development of preventive and curative measures for the potential problem of asphaltene deposition occurring during production, transport and refining operations. The question of reversibility of asphaltene precipitation, yet a controversial issue, is crucial for a clear and unequivocal understanding of the precipitation phenomenon, development of mathematical models that describe the behavior of asphaltenes in petroleum fluids, and the design of inhibitors. In this work, the behavior of precipitated asphaltenes in Brazilian crude tank oil samples following flocculant removal and gradual addition of fresh oil was investigated. The results obtained revealed a re-dissolution of precipitated asphaltene particles following flocculant removal and oil addition. On the inhibition of asphaltene precipitation, the capacity of a number of surfactants and block copolymers to inhibit asphaltene precipitation and deposition was also examined. Ethoxylated Nonylphenols and Hexadecyl Trimethyl Ammonium Bromide displayed highest capacity in the inhibition of asphaltene deposition.     

Deposition of diamond coating on pure titanium using micro-wave plasma assisted chemical vapor deposition

The nucleation and growth of diamond coatings on pure Ti substrate were investigated using microwave plasma assisted chemical vapor deposition (MW-PACVD) method. The effects of hydrogen plasma, plasma power, gas pressure and gas ratio of CH₄ and H₂ on the microstructure and mechanical properties of the deposited diamond coatings were evaluated. Results indicated that the nucleation and growth of diamond crystals on Ti substrate could be separated into different stages: (1) surface etching by hydrogen plasma and the formation of hydride; (2) competition between the formation of carbide, diffusion of carbon atoms and diamond nucleation; (3) growth of diamond crystals and coatings on TiC layer. During the deposition of diamond coatings, hydrogen diffused into Ti substrate forming titanium hydride and led to a profound microstructure change and a severe loss in impact strength. Results also showed that pre-etching of titanium substrate with hydrogen plasma for a short time significantly increased the nuclei density of diamond crystals. Plasma power had a significant effect on the surface morphology and the mechanical properties of the deposited diamond coatings. The effects of gas pressure and gas ratio of CH₄ and H₂ on the nucleation, growth and properties of diamond coatings were also studied. A higher ratio of CH₄ during deposition increased the nuclei density of diamond crystals but resulted in a poor and cauliflower coating morphology. A lower ratio of CH₄ in the gas mixture produced a high quality diamond crystals, however, the nuclei density and the growth rate decreased dramatically.     

Critical Success Factors for Different Project Objectives

The identification of key factors for construction project success enables appropriate allocation of limited resources. Most of the related past work only identified critical success factors for construction projects in general. The present study seeks to distinguish these factors according to the project objectives of budget, schedule, and quality. The analytic hierarchy process is adopted to determine the relative importance of success-related factors. A hierarchical model for construction project success is presented. Sixty-seven success-related factors are considered. These factors are grouped under four main project aspects, namely, project characteristics, contractual arrangements, project participants, and interactive processes in the hierarchical model for project success. A questionnaire was developed to facilitate systematic data collection in this study. Experts with an overall average of 20 years of experience in the construction industry were invited to participate in the survey. Critical success factors addressing budget performance, schedule performance, quality performance, and overall project success are identified. Some pertinent findings of the study are discussed. Comparisons with findings of previous studies using neural network approach are also presented.     

Crack identification using electrical impedance tomography and transfer learning

Sensing skins and electrical impedance tomography constitute a convenient and inexpensive alternative to dense sensor networks for distributed sensing in civil structures. However, their performance can deteriorate with the aging of the sensing film. Guaranteeing high identification performance after minor lesions is crucial to improving their ability to identify structural damage. In this paper, electrical resistance tomography is used to identify the crack locations in nanocomposite paint sprayed onto structural components. The main novelty consists of using crack annotations collected during visual inspections to improve the crack identification performance of deep neural networks trained using simulated datasets through transfer learning. Transfer component analysis is employed for simulation-to-real information transfer and applied at a population level, extracting low-dimensional domain-invariant features shared by simulated models and structures with similar geometry. The results show that the proposed method outperforms traditional approaches for crack localization in complex damage patterns.     

Ammonia Electrosynthesis with a Stable Metal-Free 2D Silicon Phosphide Catalyst

Metal-free 2D phosphorus-based materials are emerging catalysts for ammonia (NH₃) production through a sustainable electrochemical nitrogen reduction reaction route under ambient conditions. However, their efficiency and stability remain challenging due to the surface oxidization. Herein, a stable phosphorus-based electrocatalyst, silicon phosphide (SiP), is explored. Density functional theory calculations certify that the N₂ activation can be realized on the zigzag Si sites with a dimeric end-on coordinated mode. Such sites also allow the subsequent protonation process via the alternating associative mechanism. As the proof-of-concept demonstration, both the crystalline and amorphous SiP nanosheets (denoted as C-SiP NSs and A-SiP NSs, respectively) are obtained through ultrasonic exfoliation processes, but only the crystalline one enables effective and stable electrocatalytic nitrogen reduction reaction, in terms of an NH₃ yield rate of 16.12 µg h⁻¹ mg_cat.⁻¹ and a Faradaic efficiency of 22.48% at −0.3 V versus reversible hydrogen electrode. The resistance to oxidization plays the decisive role in guaranteeing the NH₃ electrosynthesis activity for C-SiP NSs. This surface stability endows C-SiP NSs with the capability to serve as appealing electrocatalysts for nitrogen reduction reactions and other promising applications.